) Part A. Consider the following reaction at equilibrium: C ( s )+H2O ( g )⇌CO ( g )+H2 ( g) Predict whether the reaction will shift left, shift right, or remain unchanged upon each of the following disturbances. Temperature: 150, 175, 200, 225, 250 (K) Kp 1. 0 points. 833 times 32 is equal to that. 76 A ⇌ C, K₂=2. Question: Consider the following reaction at equilibrium: 2CO2 (g) ⇄ 2CO (g) + O2 (g) ΔH° = −514 kJ Le Chatelier's principle predicts that an increase in temperature will __________. 24) Consider the following reaction. K p = K c B. jee main 2023. The following reaction proceeds only if an equivalent amount of silver fluoroborate, \(\ce{Ag}^\oplus \ce{BF_4} \: ^\ominus\), is added to the reaction mixture:. This problem has been solved! You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Assume that the initial concentration of A in each case is 1. 0 Moles of A 0. 0 g C )* (2 mols Fe 2 O 3 /3. d) a(n) increase in Keq. Consider the following reaction The correct statement for product B is. 833 times 32 is equal to that. Consider the following reaction at equilibrium: 2NH 3 (g) N 2 (g) + 3H 2 (g) Le Châtelier's principle predicts that the moles of in the reaction container will increase with _____. 2CO2(g) arrow 2CO(g) + O2(g) Calculate Delta G at 25 degrees Celsius. Question: Consider the following reaction. Which of the following will not increase the rate of the reaction? A) increasing the concentration of reactant A. (C H 3) 3 C C H (O H) C H 3 conc. 010 M. which of the above reactions (enter only the reaction number 1 to 7) shows how a solution containing a conjugate base can be converted to a buffer solution by adding a strong acid?. sf(R=k[NO]^(2)[H_2]^1) sf(k=1. X↽−−⇀Y If 𝐾c=0. Consider the following reactions. Practice: Consider the following reaction between calcium oxide and carbon dioxide: CaO(s)+CO2(g)→CaCO3(s) A chemist allows 14. 7 g of MgO ( s) is decomposed into Mg ( s) and O2 ( g) at constant pressure? Δ H =. 0 x 10^{-4} mol CH_4 and was found to raise the temperature of 18 g of water from 21. 18 kJ/K, it is not possible to predict the spontaneity of this reaction. 5 × 10 5 P Q + 1 2 R 2 ⇋ P Q R, K 2 = 5 × 10 − 3 The value of K 3 for the equilibrium 1 / 2 P 2 + 1 / 2 Q 2 + 1 / 2 R 2 ⇋ P Q R. Mixture of C6H 5CH O and HCHO is treated with NaOH, then this reaction involves: View Solution. In this case, the equilibrium constant shows that the product is A and the reactants are B and C. 0 g C; 1 mol Fe = 55. It is. Consider the reaction. The balanced chemical reaction would be B+2C−⇀↽−AB+2C↽−−⇀A. Question: Consider the following reaction at equilibrium. For Al: (3. The increasing order of the boiling points of the major products A,B and C of the following reactions will be:. ) For example, the gas-phase decomposition of cyclobutane, C 4 H 8, to ethylene, C 2 H 4, is represented by the following chemical equation:. Here are some examples to consider:. An oxidation–reduction or redox reaction is a reaction that involves the transfer of electrons between chemical species (the atoms, ions, or molecules involved in the reaction). Decreasing the volume of the reaction vessel C. Study with Quizlet and memorize flashcards containing terms like Consider the following chemical reaction: 2CH4(g) <----> C2H2(g) + 3H2(g) Describe what is happening within the system when it is at equilibrium in terms of concentrations, reactions that occur, and reaction rates. Practice: Consider the following reaction between calcium oxide and carbon dioxide: CaO(s)+CO2(g)→CaCO3(s) A chemist allows 14. KBC Multiple Choice Rate = K [CH3CH2CH2Br] o Rate = K [CH3CH2CH2Br [KOC (CH3)3] Rate = K [CH3CH2CH2Br]KOC (CH3)372 o Rate = K. 44 moles of NO2 if there is plenty of water present? 3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g), Consider the following reaction. This is because the reaction is exothermic and releases heat. When 3. Step 2: When hydrogen chloride reacts with iron metal (Fe), it forms iron (II) chloride (FeCl 2) and hydrogen gas (H 2). In a first-order reaction, the reaction rate is directly proportional to the concentration of one of the reactants. Consider the following reaction: H2 (g)+Br2 (l)⇌2HBr (g) The data in the table show the equilibrium constant for this reaction measured at several different temperatures. Thus, B is Fe. Science Chemistry Chemistry questions and answers Consider the following reaction. 300 K Express your answer using one decimal place. Temperature: 150, 175, 200, 225, 250 (K) Kp 1. The reaction that takes place is: 2NaCl + conc. Consider the following reaction: 2NO(g) + O_2(g) => 2NO_2(g) Estimate delta G^o for this reaction at each of the following temperatures and predict whether or not the reaction will be spontaneous. The equation for the heat of formation is the third equation, and ΔHr = ΔHfCH₄ -ΔHfC - 2ΔHfH₂ = ΔHfCH₄ - 0 – 0 = ΔHfCH₄. 2 P Q ⇋ P 2 + Q 2; K 1 = 2. If pure phosgene at an initial pressure of 1. an increase in total pressure by the addition of helium gas (V and T constant). 83 moles NO,. LiF (s)⇌Li++F−LiF (s)⇌LiF (aq)F−+H2O⇌HF+OH−H2O⇌H++OH−Ksp= [Li+]γLi+ [F−]γF−Kion pair = [LiF (aq)]γLiF (aq)Kb=Kw/Ka ( for HF) Kw= [H+]γH+ [OH−]γOH− Look up the. Glucose have 5 OH groups that are replaced by acetyl group so the value of Z eq is 5. -the reaction will shift left. How many molecules of Cl2 would be formed by complete reaction in each case? (Assume 100% actual yield. Consider the following reaction: O2(g) + 2 NO(g) -> 2 NO2(g) (a) The rate law for this reaction is first order in O2(g) and second order in NO(g). Consider the reaction: A (g) ⇌ B (g) + C (g) Find the equilibrium concentrations of A, B, and C for each value of Kc. Consider the following reaction. Chemistry questions and answers. 5×10-3 2. addition of a catalyst. And then I just multiply that times the molar mass of molecular oxygen. Match with the definitions that apply for the substances indicated. Loaded 0%. Consider the following reaction: \[\ce{ F2 + 2 NO2 → 2 NO2F } onumber\] Application of the "chemical intuition" mentioned in the above box would lead us to suspect that any process that involves breaking of the strong F–F bond would likely be slow enough to be rate limiting, and that the resulting atomic fluorines would be very fast to. And from the reaction equation 3 mols C = 2 mols Fe2O3. 1 4. Q 5. 40 6. Consider the following reaction at 25 °C: 3 NiO (s) + 2 NH₃ (g) → 3 Ni (s) + N₂ (g) + 3 H₂O (g) a. Consider the following reaction. 958atm, PI2=0. 27×10−6at 500 KA (aq)↽−−⇀3B (aq) If a 4. A (aq)↽−−⇀3B (aq)𝐾c=7. Which of the following is true regarding preparation of aldehydes and ketones ? (i) Both can be prepared by the oxidation of the concerned alcohol with copper at about 250 ∘ C (ii) Both can be prepared by the oxidation of the concerned alcohol by oppenauer oxidation. Consider the following reaction, xMnO4- + yC2O42- + zH+ → xMn2+ +2yCO2+z/2 H2O The values of x, y and z in the. 2CH2Cl2 (g) CH4 (g) + CCl4 (g) If the three gases are mixed in a rigid container at 350 K so that the partial pressure of each gas is initially one atm, what. Who are the experts?. (1 mole H 2 weights approximately 2 grams). 000 L of saturated MgF2 solution at 18 C to which 0. 00 M. Jan 30, 2023 · The Heat of Reaction (also known and Enthalpy of Reaction) is the change in the enthalpy of a chemical reaction that occurs at a constant pressure. 60*10^4 at 350 degree C. Consider the following reaction. 72×10-3 M SO3, 1. Which of the following statements is TRUE concerning this system? The reaction will shift in the direction of reactants. 0 mol L-s-1, at what rate is [B] changing? Not the question you’re looking for? Post any question and get expert help quickly. Study with Quizlet and memorize flashcards containing terms like Which of the following statements best describes what occurs at equilibrium? A) The reaction has stopped so the concentrations of reactants and products do not change. 5×10^27 8. Click here:point_up_2:to get an answer to your question :writing_hand:consider the following reaction sequence s 8 s 80 2 grightarrow 8so. 40 6. Answers: BC, AC, AB, C. The reaction will shift in the reverse direction C. 20 M sample of A is heated to 500 K, what is the concentration of B at equilibrium?. When treated with concentrated nitric acid, aluminium forms aluminium oxide. 44 moles of NO2 if there is plenty of water present? 3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g) A) 2. We can convert the 3. 5 kJ mol^-1 and ΔS = 83. 762 atm, respectively, at 350 degree C. If you decrease the volume of the reaction chamber, you would observe Decreasing the volume increases the pressure, which will decrease the number of molecules on the side of the reaction with more gas. Math Tutor with B. At minimum, a possible reaction mechanism must meet the following two conditions:. The third reaction: Glucose → CH 2 CO 2 O z eq of acetyl derivative. Consider the following exothermic reaction, which can be written with HEAT on the right side: 4HCl (g) + O2 (g) ⇋ 2Cl2 (g) + H2O (g) + HEATWhich of the. Temperature: 150, 175, 200, 225, 250 (K) Kp 1. Consider the. Part Consider the following reaction: 2AgNO3(aq) + MgCl2 (aq) + 2AgCl(s) + Mg(NO3)2 (aq) Enter the complete ionic. In endothermic reaction the energy of products is more than the energy of reactants so the enthalpy of reaction is positive. Assume that the initial concentration of A in each case is 1. 81 moles NO B) 25. Which of the following statements is TRUE concerning this system? The reaction will shift in the direction of reactants. Determine the value of the equilibrium constant at 25oC. Click here👆to get an answer to your question ️ consider the following reaction: CH3 - CH3 |CH - CH = CH2 [2. Consider the following reactions : A→P1 ; B →P2 ; C →P3 ; D →P4 The order of the above reactions are a, b, c, and d, respectively. Note: It wanted an. 0 mol of O3 and 1. c)an increase in the partial pressure of O2. Determine the equilibrium concentration of H2O(g). Question: Consider the following reaction and its equilibrium constant: 4 Cuo(s) + CH4(g) = CO2(g) + 4 Cu(s) + 2 H2O(g) Kc = 1. Who are the experts? Experts are tested by Chegg as specialists in their subject area. 0 g of KI is added to the H 2 O 2, bubbles of O 2 are produced at an increased rate. C2H5OH +CH3CO2H ⇌ CH3CO2C2H5 +H2O C 2 H 5 OH + CH 3 CO 2 H ⇌ CH 3 CO 2 C 2 H 5 + H 2 O. The increasing order reactivity towards addition reaction will be _____. 9 (at 25∘C) A reaction mixture at 25∘C initially contains PI2 = 0. We need to know two things in order to calculate the numeric value of the equilibrium constant: the balanced equation for the reaction system, including the physical states of each species. (C H 3) 2 C H C H. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. We can convert the 3. a)no changes in equilibrium partial pressures. 3 moles NO C) 8. the neutrons immediately take part in the fission process. Q 4. Final answer: The equilibrium constant K for the reaction C ⇌ B is calculated by dividing the equilibrium constant of reaction A ⇌ B by the equilibrium constant of reaction A ⇌ C, giving a result of 1. The KF dissolves completely. C2H5OH +CH3CO2H ⇌ CH3CO2C2H5 +H2O C 2 H 5 OH + CH 3 CO 2 H ⇌ CH 3 CO 2 C 2 H 5 + H 2 O. Answer: Increasing the temperature will cause the equilibrium to shift towards the reactants (left). From this the equilibrium expression for calculating K c or K p is derived. 27M and [H2]=0. In endothermic reaction the energy of products is more than the energy of reactants so the enthalpy of reaction is positive. H,SO н H-O + C H CH Erase Нас Rings More Select Draw C. Le Chatelier's Principle. Consider the following two reactions: A → 2B ΔH°rxn = 456. What changes in this reaction is the oxidation state of these atoms. Find step-by-step Chemistry solutions and your answer to the following textbook question: Consider the following reaction, which occurs at standard state: $$ \ce{2Cl(g) \rightarrow Cl2(g)} $$ *∆Hº* =–243. Note: It wanted an. Final answer: The equilibrium constant K for the reaction C ⇌ B is calculated by dividing the equilibrium constant of reaction A ⇌ B by the equilibrium constant of reaction A ⇌ C, giving a result of 1. 480 M SO 2 was found to contain 1. Consider the following reaction. Problem 53E: A 500-g sample of one of. In addition, predict under what temperatures (all temperatures, low temperatures, or high temperatures), if any, the reaction is spontaneous. Chemistry questions and answers. Using data from Appendix 4, determine the equilibrium partial pressure of SO2 in the mixture. (Figure 1). (Assume that ΔH∘ and ΔS∘ do not change too much within the given temperature range. In order to relate the amounts H A 2 SO A 4 and NaOH using a mole ratio, we first need to know the quantity of H A 2 SO A 4 in moles. Determine the value of ΔH for each of the following related reactions. Here’s the best way to solve it. 20 0. Chemistry. 8×10−3 180 KK 0. (Assume that ΔH∘ and ΔS∘ do not change too much within the given temperature range. 2 Kc= 1. Which of the following statements is true concerning this system?a) The reaction will shift in the direction of. A second reaction mixture, also at 175 K, contains PH2=PI2= 0. 00 moles 02 25) Identify. Coefficients become exponents. The correct option is B It has a ketone functional group. Consider the following reaction: \[\ce{ F2 + 2 NO2 → 2 NO2F }\nonumber\] Application of the "chemical intuition" mentioned in the above box would lead us to suspect that any. 0388 0. Consider the following reaction: 2 H 2 S(g)+ SO 2 (g)<=>3S(s)+2 H 2 O(g) A reaction mixture initially containing 0. The following reaction proceeds only if an equivalent amount of silver fluoroborate, \(\ce{Ag}^\oplus \ce{BF_4} \: ^\ominus\), is added to the reaction mixture:. Consider the following reaction: N 2 O 4 g ⇌ 2 NO 2 g; ∆ H ° = + 58 kJ For each of the following cases (a, b), the direction in which the equilibrium shifts is: (a) Temperature is. ) express your answer as an integer a)HCL=7, 02=1 B)HCL=6, O2=3 C)HCL=4, O2=5. From this the equilibrium expression for calculating K c or K p is derived. H2(g) + CO2(g) H2O(g) + CO(g) (a) Laboratory measurements at 986 C show that there are 0. Temperature: 150, 175, 200, 225, 250 (K) Kp 1. About us. (C H 3) 2 C H C H (B r) C H 3 alc. 4×10^21 Part A Use the data to find. 124 mol of A and allowed to react to form B according to the reaction A(g) → B(g). addition of a catalyst. Class 12 CHEMISTRY NTA JEE MOCK TEST 30. Consider the following reaction. 33A reaction mixture contains 0. Consider the reaction. See Answer. 8 (c) 2,5 and 16 (d) 5, 2 and 8. Here’s the best way to solve it. Click here:point_up_2:to get an answer to your question :writing_hand:consider the following reactionabrightleftharpoons e k c 62bcrightleftharpoons 2d k c 4what will. 4 kJ Which has the higher, more positive, enthalpy under these conditions, 2Cl(g) or Cl 2 (g)?. 70atm for x in the last row of our ICE table, we can now find the equilibrium partial pressures for the two gases: P H 2 = 2 x = 1. Question: Consider the following reaction: 2O3(g)→3O2(g) The rate law for this reaction is as follows: rate=k[O3]2[O2] Suppose that a 1. 3 E) 0. 010 M. This is a restatement of law. ) For example, the gas-phase decomposition of cyclobutane, C 4 H 8, to ethylene, C 2 H 4, is represented by the following chemical equation:. Question: Solubility with activity. Consider the reaction. 5 kJ mol^-1 and ΔS = 83. Examine the three figures representing equilibrium concentrations in this reaction at the same temperature for the three different hal- ogens. Step by step video & image solution for Consider the following reaction Which of these reactions are possible ? by Chemistry experts to help you in doubts & scoring excellent marks in Class 12 exams. 845 + 3*15. 958atm, PI2=0. the fan van xxx
Because the concentration of hydrogen is greater than what is needed for complete reaction, the concentration of unreacted hydrogen in the reaction mixture would be 0. . Consider the following reaction
Non-elementary steps, or complex reactions, are sets of elementary reactions. 0 g C * (1 mol C /12. (Assume that ΔH∘ and ΔS∘ do not change too much within the given temperature range. (Assume that ΔH∘ and ΔS∘ do not change too much within the given temperature range. The reaction will shift in the reverse direction C. The equilibrium constant expression has two terms in the numerator. C is added to the reaction mixture. Band of Stability: Beta Decay 2m. See Answer. Consider the following reaction: 2 Mg + O_2 \rightarrow 2MgO \space \space \Delta H_{rxn} = -1203 KJ Calculate the amount of heat (in kJ) associated with complete reaction of 4 moles of Mg. ½H2(g) + ½I2(g) → HI(g), ΔH = +6. s^(-1)) This question is concerned with the method of initial rates which can be used if more than one species is reacting. This is because the reaction is exothermic and releases heat. 300 1. C2H5OH +CH3CO2H ⇌ CH3CO2C2H5 +H2O C 2 H 5 OH + CH 3 CO 2 H ⇌ CH 3 CO 2 C 2 H 5 + H 2 O. If you go three significant figures, it's 26. If you decrease the volume of the reaction chamber, you would observe Decreasing the volume increases the pressure, which will decrease the number of molecules on the side of the reaction with more gas. The differential rate law for the simplest second-order reaction in which 2A → products is as follows: rate = −Δ[A] 2Δt = k[A]2 (14. 200 0. Consider the following reaction: N 2 O 4 g ⇌ 2 NO 2 g; ∆ H ° = + 58 kJ For each of the following cases (a, b), the direction in which the equilibrium shifts is: (a) Temperature is. Consider the following reaction: N 2 O 4 g ⇌ 2 NO 2 g; ∆ H ° = + 58 kJ For each of the following cases (a, b), the direction in which the equilibrium shifts is: (a) Temperature is. An arrow is drawn between the reactants and products to indicate the direction of the. It states that in an elimination reaction the major product is the more stable alkene with the more highly substituted double bond. If 2. (2) racemic mixture and is neutral. every neutron released in the fission reaction initiates further. Find the concentrations of the major species in a saturated aqueous solution of LiF. Jul 12, 2023 · An example of the former is a dimerization reaction, in which two smaller molecules, each called a monomer, combine to form a larger molecule (a dimer). A second reaction mixture at the same tempera; Consider the following reaction: 2H_2S + SO_2 to S(s)+H_2O. See Answer. May 9, 2021 · N2 (g) + 3 H2 (g) ↔ 2 NH3 (g) ΔH = −92kJ/mol. T (K) [N2] [H2] [NH3] [Kc] 500 0. Draw the major alkene elimination products from each of the reactions. Temperature: 150, 175, 200, 225, 250 (K) Kp 1. Chemical reactions. 40 atm. (C H 3) 3 C C H (O H) C H 3 conc. What is the partial pressure of NOBr in this mixture?. no change will be observed. 00 moles 02 D) 16. (C H 3) 2 C H C H (B r) C H 3 alc. Consider the reaction 2A + B C+ D Following results were obtained in experiments designed to study the rate of reaction : Exp. Non-elementary steps, or complex reactions, are sets of elementary reactions. Open in App. (2) racemic mixture and is neutral. Consider the following reactions : 'A' is - asked Sep 11, 2020 in Chemistry by AmarDeep01 (50. Assuming that there is no product at the beginning of the reaction and that at equilibrium [CO] = 0. A) increase the partial pressure of O2 (g) B) decrease the partial pressure of CO2 (g) C) decrease the value of the equilibrium constant D) increase the. In this reaction, glucose directly reacts with CH 3 CO 2 O and OH group present in glucose is replaced by an acetyl group to form an acetyl derivative. Study with Quizlet and memorize flashcards containing terms like What is ΔHΔH for the reaction 3C→2B3C→2B?, Consider the following reaction: 2 A + 3 B → D ΔHrxn = 45. at low. asked Aug 10, 2022 in Chemistry by SujitTiwari (51. 124 mol of A and allowed to react to form B according to the reaction A(g) → B(g). Question: Consider the following reaction: 4HCl(g)+O2(g)?2H2O(g)+2Cl2(g)Each of the following molecular diagrams represents an initial mixture of the reactants. A2 + 2B → 2AB (overall reaction) Mechanism A2 ↔ 2A fast A + B → AB slow, Analyzing a new reaction Consider the following elementary steps that make up the mechanism of a certain reaction: What is the overall reaction?. Here, we have two. 010 M. 0 moles of A are converted into products at a pressure of 1. As an example, consider the following reaction, \[ A + 3B + 2C \rightarrow \text{products} onumber \] whose experimental rate law is given by:. 9×10^22 250 1. Consider the following reaction: 2 H 2 S(g)+ SO 2 (g)<=>3S(s)+2 H 2 O(g) A reaction mixture initially containing 0. The decomposition of ozone, for example, appears to follow a mechanism with two steps: O3(g) O2(g) + O O +O3(g) 2O2(g) O 3 ( g) O 2 ( g) + O O + O 3 ( g) 2 O 2 ( g). ΔG∘rxn Δ G r x n ∘ = kJ Part B at equilibrium Express your answer in kilojoules. Identify the final product [D] obtained in the following sequence of reactions. 0 points. Question: Consider the following reaction: 4HCl(g)+O2(g)?2H2O(g)+2Cl2(g)Each of the following molecular diagrams represents an initial mixture of the reactants. Question: Consider the following reaction. , Consider the following reactions: A → 2B; ΔH = x kJ B → C; ΔH = y kJ What would be the enthalpy change associated with the reaction below? A → 2C x - y x + 2y x + y 2x + y, Select the answer that best completes the following sentence. This problem has been solved! You'll get a detailed solution from a subject matter expert that helps you learn core concepts. Similar Questions. Use the information here to determine the value of ΔSsurr at 355 K. NO20g)O29)O3 (g) + NOg) K2 1. As an example, consider the following reaction, \[ A + 3B + 2C \rightarrow \text{products} onumber \] whose experimental rate law is given by:. The equilibrium constant expression has two terms in the numerator. Write the equilibrium expression ( K) for each of the following reactions. None of the other answers is correct. 009 10. Jan 30, 2023 · The Heat of Reaction (also known and Enthalpy of Reaction) is the change in the enthalpy of a chemical reaction that occurs at a constant pressure. Consider the following two reactions: A → 2B ΔH°rxn = 456. 0 atm, respectively. 6 g of CaCO3. 10 0. Kc = [Hg]2 [O2] Explanation: Solids and liquids are not included in the K expression. The average rate of appearance of B is given by Δ[B]/Δt. Mixture of C6H 5CH O and HCHO is treated with NaOH, then this reaction involves: View Solution. To solve the second part, you start with 32. Click here 👆 to get an answer to your question ️ Consider the following reactions : ‘A’ is: (A) CH₂ = CH₂ (B) CH₃ – C ≡ CH (C) CH ≡ CH (D) CH₃ – C ≡ C – CH₃. The balanced equation will appear above. When 1 mol each of C 2 H 5 OH and CH 3 CO 2 H are allowed to react in 1 L of the solvent dioxane, equilibrium is established when 13 1 3 mol of each of the reactants remains. Decreasing the partial pressure of H2O (g). 184 joules, Anytime a system is. Step 4: multiply steps 2 and 3 together: 9. From this the equilibrium expression for calculating K c or K p is derived. Now we can set up an equilibrium expression for the reaction and solve for K p : K p = ( P H 2) 2 ⋅ P O 2 = ( 1. Question: Consider the following reaction. Indicate True (T) or False (F) for each of the following: 1. Consider the following energy diagram and determine which of the following statements is true. B) increasing the concentration of reactant B. Express your answer as a net ionic equation. From this the equilibrium expression for calculating K c or K p is derived. B) The amount of products are equal to the amount of reactants. For a given reaction, ΔH = 35. In contrast, recall that according to Hess’s Law , \(ΔH\) for the sum of two or more reactions is the sum of the ΔH values for the individual reactions. . sukihana and kill bill, jeff grubb twitter, sexy nude brunette, studio apartments reno, niurakoshina, toonsex, charlie damelio twerking, subnautica thermal plant, femjoi, 5k porn, jobs san marcos tx, craigslist san diego boats for sale by owner co8rr